Re: MALDI: Protein dimmer

From: Ioannis A. Papayannopoulos (ioannis_papayannopoulos@yahoo.com)
Date: Fri Apr 14 2000 - 08:17:37 EDT


The dimer is most likely a result of MALDI mass spectrometry analysis, and commonly observed for proteins, especially in concentrated samples.. You were correct in trying to find the triply charged dimer peak; it's absence, although not constituting conclusive proof, would support the notion that the dimer is, indeed, formed in the mass spectrometer during ionization. However, as far as I know, short of doing size exclusion chromatography (or, perhaps, non-denaturing PAGE) you can not say with absolute certainty that the dimer is, indeed, a feature (aka artifact) of mass spectrometry.

Ioannis Papayannopoulos

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